화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2011년 가을 (11/02 ~ 11/04, 경원대학교)
권호 15권 2호
발표분야 [에너지저장변환
제목 Preparation and electrochemical characterization of polymer composite electrolytes Based on poly(ethylene oxide)-poly(vinylidene fluoride) blend containing ceramic filler
초록 Solid polymer electrolytes (SPEs), which are composed of poly(ethylene oxide)-poly(vinylidene fluoride) matrix, BaTiO3, and lithium salt, propylene carbonate were prepared in order to study the influence of BaTiO3 content on the electrochemical characterization of the composites. The ionic conductivity of the SPEs was monitored by AC impedance, and the crystallinity of the SPEs was evaluated by using XRD, and the morphology of the SPEs was observed by SEM image. The studies of porosity, crtstallinity and ionic conductivity of solid polymer electrolytes were performed as a function of BatiO3 content. The addition of BatiO3 can greatly enhance the Li ion behavior and ionic conductivity of polymer electrolytes. Also, these ion conductivity characteristics are dependent on crystallinity with BatiO3 content.
저자 이륜규, 김석
소속 부산대
키워드 polymer composite electrolytes; ceramic filler
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