화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 가을 (10/22 ~ 10/23, 일산 KINTEX)
권호 15권 2호, p.2318
발표분야 촉매 및 반응공학
제목 Studies on theReforming ofN-Hexadecane over Ca-ModifiedNi-based Hydrotalcite Catalyst
초록 Recently, hydrogen production by steam reforming of liquid hydrocarbons has been received much attentions for application in fuel processor system. In this work, steam reforming of n-hexadecane (n-C16H34) was investigated over Ca modified Ni-based hydrotalcite-like catalysts. Steam reforming was carried out in a temperature range of 750 ~ 950 ℃, at atmospheric pressure with a space velocity of 10,000 h-1 H2O/C molar ratio of 3.0 in a fixed bed reator system. The prepared catalysts were analyzed by N2 Physisorption, CO Chemisorption, TPR, XRD, SEM and TEM techniques. These results showed that Ca metal modified Ni/MgAl catalyst described higher catalytic activity under the tested conditions even though filamentous carbon was formated during the steam reforming of n-hexadecane.
저자 김소정1, 문동주1, 이윤주2, 김대현2, 이승환2, 이상득2, 임태훈2, 이병권2
소속 1KIST / UST, 2KIST
키워드 hydrotalcite; Desel; reforming
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