화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터)
권호 16권 2호, p.1774
발표분야 에너지
제목 Steam Reforming of Synthetic Diesel over Rh-modified Ni basedCatalysts
초록 Steam reforming of synthetic dieselover Rh-midified Ni based hydrotalcite catalyst was carried out at 800 ℃ at atmospheric pressure,space velocity of 10,000 h-1 and feed molar ratios of Steam/C =1.0~3.0.Rh-modified Ni based hydrotalcite catalyst (Rh-Ni/MgAl) was prepared by a solid phase crystallization (spc) method, and characterized by N2 physisorption, CO chemisorption, TPR, TPO, XRD, and TEM techniques. The H2 selectivities over modified hydrotalcite catalysts was obtained 63~73% in steam reforming of synthetic diesel.It was found that Rh-Ni/MgAl catalyst showed higher catalytic stability andlesscarbon formation thanspc-Ni/MgAl catalysts under the tested conditions. The results suggest that Rh-Ni/MgAl catalyst may be applied for thesteam reformingof diesel.
저자 이승환, 정재선, 이윤주, 이병권, 이상득, 문동주
소속 한국과학기술(연)
키워드 Diesel; Steam Reforming; hydrotalcite; Rh-Ni/MgAl catalyst
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