| 학회 |
한국화학공학회 |
| 학술대회 |
2014년 봄 (04/23 ~ 04/25, 창원컨벤션센터) |
| 권호 |
20권 1호, p.969 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Polymer-supported DABCO for Transesterification of dimethyl carbonate with glycerol |
| 초록 |
DABCO (1,4-diazabicyclo[2.2.2]octane) was immobilized on Merrifield peptide resin and characterized using solid state 13C-NMR and IR. the results showed the DABCO was successfully immobilized on the surface of the Merrifield resin. Acid-base titratiion of Merrifield resin-supported DABCO revealed 2.17 mmol/g of basic site exist on the prepared catalyst. Merrifield resin-supported DABCO is highly active heterogeneous catalyst for synthesis of glycerol carbonate from glycerol and dimethyl carbonate and could be reused at least 5 times without losing its catalytic activity. |
| 저자 |
Fidelis Simanjuntak, 안병성, 이상득, 이현주
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| 소속 |
KIST |
| 키워드 |
glycerol; glycerol carbonate; Merrifield resin; DABCO; heterogeneous catalyst
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| E-Mail |
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| 원문파일 |
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