화학공학소재연구정보센터
학회 한국화학공학회
학술대회 1998년 가을 (10/23 ~ 10/24, 조선대학교)
권호 4권 2호, p.3005
발표분야 에너지/환경
제목 토양에서의 pesticides의 동역학적인 고찰
초록 The time evolution of extractable remaining pesticides shows generally two time
scales while they are decomposed. It could be interpreted as that initial pulse input ofpesticide begins to decompose as well as to change its state into that of bound-residueand once pulse input decays and bound-residue develops, bound-residue changes itsstate into the decomposable pesticide and finally decomposes. We suggest a kineticmodel that can qualitatively and quantitatively explain the decomposition of pesticideand the shift of its vulnerable state against microbe’s attack, soil catalytic activity, orother possible decomposition activity. At very low concentration of pesticide, ourmodel reduces to Hamaker and Goring’s model and the effect of model-inducednonlinearity diminishes. The kinetic rate constants of each pesticide in paddy and uplandsoil are statistically determined, using Kirkpatrick’s simulated annealing method tosearch the global minima.
저자 임광희, 이영득
소속 대구대
키워드 soil-bound residue; extractable residue; soil environment; persistence; kinetic modeling
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