화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터)
권호 39권 1호
발표분야 고분자구조 및 물성
제목 Water-based preperation of graphene/polyaniline composite and their characteristics
초록 A new and facile modification method to endow graphene with a water-dispersibility was provided in this study. The remnant epoxide group on the graphene prepared by thermal reduction of graphite oxide and the amine group of potassium 6-aminocaproate reacted effectively by a simple heating process at solid state of the mixture mixed in a solvent and dried. The modified graphene with negatively charged carboxylate moiety dispersed easily and stably in water. The graphene/polyaniline (PANI) composite was prepared in aqueous system by a simple physical mixing of aqueous dispersions of negatively charged graphene and positively charged micron-size PANI particles, followed by drying. The composites mostly exhibited higher energy storage capacities as a supercapacitor electrode compared to those of graphene or PANI themselves. The synergistic effect was most evident at graphene/PANI weight ratio of 20/80. It exhibited more than two-fold of the specific capacitances of PANI or graphene.
저자 간수크1, 이태민2, 다오1, 보옥황1, 김병수2, 정한모1
소속 1울산대, 2UNIST
키워드 Graphene; Polyaniline; Water dispersible graphene
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