화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 기능성 고분자
제목 Surface Polymerization of Sulfur Cathode for High Performance Li/S Battery
초록 Sulfur has been recognized as a promising cathode material for future Li-ion battery. However, the sulfur cathode suffers from polysulfide shuttle during cycling, limiting its practical applications. Hence, there has been current research to suppress the polysulfide shuttle for long term stability. The general strategy to overcome this problem is encapsulation of sulfur particle by carbon or conductive polymer. However, volume change during cycling produces mechanical stress and it can degrade coating layer due to the weak interaction between coating material and sulfur. Moreover, the general method requires large amount of coating material, which will reduce energy density. We have developed a novel anchoring and surface polymerization method to solve these issues. The preparation and properties of newly-developed system will be discussed in detail.
저자 김태현, 임상현
소속 인천대
키워드 Sulfur cathod; Li ion battery; surface polymerization
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