화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 봄 (04/12 ~ 04/13, 제주 ICC)
권호 32권 1호
발표분야 고분자 구조 및 물성
제목 Synthesis and Characterization of Modified Cyclodextrin/Poly(methyl methacrylate) Copolymer
초록 Modified cyclodextrin-poly(methyl methacrylate) copolymers were prepared from modified cyclodextrin and poly(methyl methacrylate) by radical polymerization. NCO group of 2-isocyanatoethyl methacrylate(IEM) and hydroxyl group of cyclodextrin can be easily reacted. These copolymers were analyzed by means of NMR spectroscopy, Gel Permeation Chromatography (GPC), IR spectra, UV-vis transmission spectra, X-Ray Diffraction(XRD), Thermogravity analysis(TGA) and Differential Scanning Calorimeter(DSC). The cyclodextrins of these copolymers showed a larger possibility of forming inclusion complex with various polymers. The copolymers were also compared with cyclodextrin/ poly(methyl methacrylate) blend.
저자 임지한1, 이원기2, 하창식1
소속 1부산대, 2부경대
키워드 cyclodextrin; inclusion complex; 2-isocyanatoethyl methacrylate
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