| 학회 | 한국화학공학회 |
| 학술대회 | 2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터) |
| 권호 | 23권 2호, p.1910 |
| 발표분야 | 에너지 환경 |
| 제목 | CO2 adsorption on Li/ Na-promoted surface of binary oxide solid-solution, MO-MO (M = Mg, Ca, Sr and Ba) |
| 초록 | Searching for promising solid sorbents for carbon dioxide (CO2) capture has been conducted for many years. MgO is one of the remarkable alkaline-earth metal oxides for carbon capture due to its abundance, low cost, and the low heat of absorption [1]. However, MgO does not have high adsorption capacity of CO2 [2]. On the other hand, CaO is another promising candidate for CO2 removal in industrial applications because of its low cost and high CO2 capture capacity [3]. In this work, we investigated CO2 adsorption on (100) surface of Li or Na-promoted solid-solution of binary oxides, using density functional theory (DFT) calculations. Firstly, we calculated the CO2 adsorption energies on (100) surface of solid-solution, such as MgO-CaO, CaO-SrO and SrO-BaO. Secondly, the effect of these Li and Na promoters on the CO2 adsorption on these surfaces were examined. References [1] B. Feng, H. An, E. Tan, Energy Fuels, 21 (2007) 426-434. [2] Q. Wang, J. Luo, Z. Zhong, A. Borgna, Energ. Environ. Sci., 4 (2011) 42-55. [3] R. Philipp, K. Fujimoto, J. Phys. Chem., 96 (1992) 9035-9038. |
| 저자 | 장준민, 강성구 |
| 소속 | 울산대 |
| 키워드 | 친환경 |
| 원문파일 | 초록 보기 |
