학회 |
한국고분자학회 |
학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
권호 |
35권 2호 |
발표분야 |
대학원생 구두발표 |
제목 |
Facile Synthesis of Monodisperse Core-Shell and Hollow Nanoparticles Based on a Charged Polymer Nanosphere or Magnetite Nanoparticle Template |
초록 |
A series of core-shell and hollow nanoparticles were prepared using various templates such as monodisperse polymer nanospheres and nanosized iron oxide particles. The nanoparticles of polymer core/silica or titania shell were prepared by sol-gel processing based on monodisperse, cationic polymer nanosphere templates, synthesized by emulsifier-free emulsion polymerization. These polymer nanospheres were subsequently treated with titania or silica inorganic precursors to form various organic core-inorganic shell hybrid nanoparticles. By the addition of a cationic surfactant in the reaction mixture, we obtained a mesoporosity in the silica shell phase. The magnetite core/titania shell nanoparticles were synthesized by layer-by-layer (LbL) self assembly method. The hollow titania or silica nanospheres were prepared by either calcination of the polymer cores at 500℃ or etching the magnetite in HCl. |
저자 |
임민호, 전진아, 하재희, 전공주, 권용구
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소속 |
인하대 |
키워드 |
core-shell; hollow nanoparticles; iron oxide; sol-gel
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E-Mail |
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