| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터) |
| 권호 |
36권 1호 |
| 발표분야 |
고분자가공/복합재료 |
| 제목 |
Investigation of Propylene Transport in Ionic Liquid andApplication of Facilitated Olefin Transport Membrane |
| 초록 |
This is a first trial of room temperature ionic liquids as an olefin carrier for facilitated olefin transport, where reversible interactions between ILs and olefin such as propylene occur to form complexes of free cations of ILs with propylene. The formation of free cations, as confirmed from slight shift of N-O stretching band upon propylene exposure by FT-IR spectra and also from quantum mechanical ab initio calculations, may be induced from interactions between the cations and olefin molecules. The transient sorption behavior of propylene in ionic liquid did not coincide with Fickian transport due to the reversible interactions, whereas non-interacting propane did. Moreover, the absorbed propylene was totally desorbed under vacuum condition, indicating that the interaction is reversible. It was thus concluded that imidazolium cations of ionic liquids can act as an olefin carrier for facilitated transport based on their selective, reversible interactions. |
| 저자 |
이정현1, 최형우2, 전성현1, 원종옥2, 강용수1
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| 소속 |
1WCU program, 2한양대 |
| 키워드 |
membrane; gas separation; facilitated transport membrane; composite membrane
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| E-Mail |
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