| 학회 | 한국고분자학회 |
| 학술대회 | 2005년 봄 (04/14 ~ 04/15, 전경련회관) |
| 권호 | 30권 1호, p.286 |
| 발표분야 | 분자전자 부문위원회 |
| 제목 | Macroscopic Nonlinear Optical Property of Tricyanopyrrolidene Chromophores containing Amorphous Polycarbonate: Effect of Molecular Kink Moiety in the Conjugative Structure |
| 초록 | Organic nonlinear optical (NLO) materials provide strong potential advantages for second harmonic generation and electro-optic application and are considered as most promising candidates for application in electro-optic and photonic devices. In this study, tricyano-pyrrolidene chromophores were synthesized as key materials for thin-film electro-optic (EO) device. These molecules were prepared in order to compare their macroscopic nonlinear optical (NLO) properties with the conjugated structure through long molecular axis. Thiophene or phenyl ring was tethered to the conjugated ethylenic bond, playing as a kink moiety to disrupt the planarity of the chromophore slightly. Real time pole and probe method was employed to investigate the change of the EO signal during poling. EO properties and their relaxation behaviors of the guest-host systems containing synthesized chromophores were investigated thoroughly. References 1. Y. Shi, C. Zhang, H. Zhang, J.H. Betchel, L. R. Dalton, B.H. Robinson, W.H. Steier, Science 2000, 288, 119. 2. Dalton, L.R.; Harper, A.W.; Wu, B.; Ghosen, R.; Laquin-danum, J.; Liang, Z.; Hubble, A.; Xu, C.; Adv. Mater, 1995, 7, 519-540. 3. Dalton, L.R.; Harper, A.; Ren, A.; Wang, F.; Todorova, G.; Chen, J.; Zhang, C.; Lee. M.; Ind. Eng. Chem. Res. 1999, 38, 8-33. 4. M. Lee, H. E. Katz, C. Erben, D.M. Gill, P. Gopalan, J.D. Heber, D.J. McGee, Science 2002, 298, 1401. |
| 저자 | 조민주1, 이상규1, 김고운1, 전웅기2, 최동훈1 |
| 소속 | 1고려대, 2고려대 Science Research Center |
| 키워드 | Nonlinear optic; electro-optic |
