화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2008년 봄 (05/09 ~ 05/10, 한양대학교(안산))
권호 12권 1호
발표분야 정밀화학
제목 Synthesis and Characterization of Poly(ferrocenylsilole) via Thermal Ring-Opening Polymerization(ROP)
초록 In recent years, organometallic polymer containing silole unit has been a topic of interest because of the wide range of optical, electrical and luminescent properties. In previous work, we synthesized silole-bridged[1]ferrocenophane from the reaction of 1,1-dichloro-2,3,4,5,-tetraphenylsilole[C4Ph4SiCl2] with ferrocene[Fe(η-C5H4)2] and n-BuLi. In this work, we have synthesized Poly(ferrocenylsilole) via the Thermal Ring-Opening Polymerization(ROP). characteristics of the poly(ferrocenylsilole) were investigated by gel permeation chromatography(GPC), 1H- and 13C- NMR spectroscopy.
저자 손홍래, 정경선, 조성동
소속 조선대
키워드 ferrocene; polyferrocenylsilole; ring-opening polymerization
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