초록 |
In recent years, organometallic polymer containing silole unit has been a topic of interest because of the wide range of optical, electrical and luminescent properties. In previous work, we synthesized silole-bridged[1]ferrocenophane from the reaction of 1,1-dichloro-2,3,4,5,-tetraphenylsilole[C4Ph4SiCl2] with ferrocene[Fe(η-C5H4)2] and n-BuLi. In this work, we have synthesized Poly(ferrocenylsilole) via the Thermal Ring-Opening Polymerization(ROP). characteristics of the poly(ferrocenylsilole) were investigated by gel permeation chromatography(GPC), 1H- and 13C- NMR spectroscopy. |