| 학회 |
한국고분자학회 |
| 학술대회 |
2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
| 권호 |
41권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Synthesis of Sulfur-Rich Polymer Nanoparticles through Interfacial Polymerization in Water and Their Surface Modification |
| 초록 |
Sulfur exhibit an array of desirable properties, but there is a limitation in processing because of low solubility in common solvents. In order to fully exploit the desirable properties of elemental sulfur, methods to obtain high sulfur-content materials in processable forms are crucial. We herein report the synthesis of sulfur-rich polymer nanoparticles from the interfacial polymerization of sodium polysulfide and 1,2,3-trichloropropane in water. Aqueous sodium polysulfide is prepared by dissolving elemental sulfur in sodium sulfide solutions. The treatment of the sodium polysulfide solution with 1,2,3-trichloropropane in the presence of suitable surfactants affords well-defined nanoparticles. The surface of polysulfide nanoparticles could be further functionalized by using end-modified surfactants followed by thermally induced radical addition reaction. The method allows for the preparation of stable polysulfide nanoparticles with positively charged surfaces. |
| 저자 |
박정민1, 정언호1, 임지우1, 차국헌1, Jeffrey Pyun2
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| 소속 |
1서울대, 2Univ. of Arizona |
| 키워드 |
Sulfur; Nanoparticle; Interfacial Polymerization
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| E-Mail |
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