| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
38권 2호 |
| 발표분야 |
기능성 고분자 (포스터발표만 진행) |
| 제목 |
Thermoresponsive Amphiphilic Star Block Copolymer Photosensitizer: Smart BTEX Remover |
| 초록 |
Thermosensitive well-defined amphiphilic star block copolymer photosensitizers were synthesized by sequential block copolymerization of styrene and N-isopropyl acrylamide from a photocatalyic porphyrin core through RAFT process. Obtained starpolymers were applied for water purification system, which removed the toxic organic materials such as benzene,toluene,ethylbenzene,xylene (BTEX) in water, following the procedure that absorbed BTEX near to the porphyrin core by effective hydrophobic interaction and then decomposed them under UV irradiation by activated singlet oxygen. The combination of starpolymers with UV irradiation effectively decomposed BTEX approximately over 95% except for Toluene, which relatively high performance comparing to other combinations such as only UV, only starpolymers and starpolymers with visible light. Finally, the function of dehydration of PNiPAM outer layer led easy to recycle starpolymers by a simple filtration after thermal treatment. |
| 저자 |
조계룡1, 김지은2, 윤호규2, 황승상1, 백경열2
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| 소속 |
1고려대, 2KIST |
| 키워드 |
starpolymer; photocatalyst; BTEX
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| E-Mail |
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