화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 봄 (04/10 ~ 04/11, 컨벤션 뷰로(대전))
권호 33권 1호
발표분야 기능성 고분자
제목 Effect of Alkyl Side-chain Length on the Luminescent Characteristics of Poly(3-n-alkylthiophene) nanoparticle and Formation of Poly Alkylthiophene / Methylmethacrylate (core/shell) nanoparticles by Oxidative Polymerization in Emulsion Polymerization
초록 Polythiophenes(PTs) are one of the most important classes of conjugated polymers, with a wide range of applications, such as conducting films, electrochromics, and field-effect transistors. Polyalkylthiophenes(PATs) can easily produce a red color that is difficult to achieve with other conjugated polymers. Furthermore, very high-efficiency PLEDs have been demonstrated with some thiophene-derived copolymer. PT nanoparticles by emulsion polymerization are decreased photoluminescence efficiency through oxidant (O2, H2O, etc). Methyl methacrylate(MMA) is transparent, able to protect, prepared monodisperse nanoparticle. Objective of this work is on the investigation about property of poly(AT/MMA) (core/shell) structures by emulsion polymerization using FeCl3/H2O2 in aqueous medium.
저자 윤승민, 이선종, 조대현, 김중현
소속 연세대
키워드 polyalkylthiophenes; nanoparticles; oxidative polymerization; particle nucleation; emulsion process; core/shell; polymer light emitting diode(PLED)
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