화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 고분자 합성
제목 Diphosphinoamine Ligands for Chromium-Catalyzed Selective Ethylene Oligomerization
초록 A series of diphosphinoamine ligands bearing amine groups were prepared. Metallation of the ligands afforded the corresponding chromium complexes for ethylene trimerization or tetramerization, which were used in ethylene oligomerizaton in the presence of MAO. It was observed that the structure of the ligands and the reaction conditions had significant influences on catalytic activities and 1-alkene selectivities.
저자 사석필1, 이용호2, 조민석2, 김상율1
소속 1KAIST, 2LG화학
키워드 polyolefin; ethylene trimerization; ethylene tetramerization
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