| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO)) |
| 권호 |
21권 2호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
Identification of active site in Mo3S13 nanocluster for electrochemical hydrogen production |
| 초록 |
Mo3S13 from amorphous MoS3 were deposited on oxidized CNT to prepare highly efficient electrocatalyst for electrochemical hydrogen production. During the reaction, transition process of Mo3S13 from MoS3 were investigated. As synthesized Mo3S13/O-CNT shows excellent electrochemical HER performance and stability for 1,000 cycles with low overpotential at 10 mA/cm2 (-137 mV) and Tafel slope (40 mV/decade).Electrochemically active sites of Mo3S13/O-CNT nanocomposites were identified by heat treatment. Control of sulfur configuration such as bridge S, apical S, and terminal S in structure of Mo3S13 were observed depending on temperature. The electrochemical HER activity of Mo3S13/O-CNT were also varied due to the configuration of sulfur. |
| 저자 |
이철호1, 조성무2, 조한익3, 이도창4, 이성호2
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| 소속 |
1한국과학기술원 / 한국과학기술(연), 2한국과학기술(연), 3건국대, 4한국과학기술원 |
| 키워드 |
molybdenum sulfide; hydrogen; CNT; Mo3S13
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| E-Mail |
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