화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center))
권호 21권 1호
발표분야 에너지저장변환
제목 Effects of conjugated bases as a TiO2-surface modifier on the open circuit voltage of solar cells
초록 Titanium dioxide (TiO2) has been most frequently used as an anodic material in a dye-sensitized solar cell (DSSC) due to its predominant chemical stability and moderate charge transport capability. However, the injected electrons into TiO2 layer can possibly go back to the sensitizer or the electrolyte due to an electron recombination phenomenon. This back electron transfer causes a diminution in conversion efficiency; hence many researchers have investigated modifications to the TiO2 layer. In this study, we report the preparation of surface-modified TiO2 electrodes using conjugate bases of weak acids and effects of the modification on the photovoltaic properties of DSSCs. The open circuit voltage of DSSCs with surface-modified TiO2 layers was improved with increasing basicity of the conjugated base.
저자 최근영1, 신동원1, 김수빈1, 성혜경1, 조성일1, 이상주2, 성시준2, 한윤수1
소속 1대구가톨릭대, 2대구경북과학기술원
키워드 Titanium dioxide; surface modification; dye-sensitized solar cells; open circuit voltage
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