화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 기능성 고분자
제목 Efficient Binary Organic Redox Mediators in Dye-Sensitized Solar Cells based on Carbon Black Counter Electrode
초록 Dye-sensitized solar cells (DSCs) have achieved energy conversion efficiencies of over 11 % with an electrolyte based on an iodide/triiodide (I-/I3-) redox shuttle. Even though the I-/I3- works efficiently, it retains however some drawbacks such as visible light absorption and metal electrode corrosion. Herein, we present a binary organic redox mediator combining two different thiolate/disulfide redox couples. Aiming at the increment of fill factor, carbon black counter electrode was applied on binary redox couples-based DSCs to reduce the charge transfer resistance at the counter electrode. As a result, we achieved 1.57 times improvement in efficiency under standard illumination conditions.
저자 조우형, 강용수, 송동훈, 편용범, 채화석, 김태언
소속 한양대
키워드 DSCs
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