| 학회 | 한국공업화학회 |
| 학술대회 | 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO)) |
| 권호 | 21권 2호 |
| 발표분야 | (국제협력) 우수 외국인 연구자 세션 |
| 제목 | Homogeneous oxidation of 5-Hydroxymethyl-2-furaldehyde (HMF) to 2,5 Furandicarboxylic acid (FDCA) |
| 초록 | 2,5 Furandicarboxylic acid (FDCA) is considered one of the top 12 building block compounds derived from biomass that can lead to a sustainable development of a new chemical platform. FDCA has a potential as the replacement for terephthalic, isophthalic, and adipic acid, which are widely used components in the polymer industry. In this research, we focused on the homogeneous oxidation of 5-Hydroxymethyl-2-furaldehyde (HMF) using N-Hydroxyphthalimide (NHPI) or N-Hydroxysuccinimide (NHSI) together with metal co-catalyst. The desired product, FDCA, is achieved through 3 steps of oxidation as shown in the scheme below. Several metal co-catalysts and solvents were screened and optimized for the reaction. Results show that partial oxidation was achieved and the major product was 2,5-Furandicarboxaldehyde (DFF). New experimental conditions are being tested to further push the oxidation of DFF in order to achieve higher selectivity of FDCA. |
| 저자 | Huynh Thanh Thien Nhan, 이경원, 문다솜, 박석규, 조진구 |
| 소속 | 한국생산기술(연) |
| 키워드 | 2; 5 Furandicarboxylic acid (FDCA); 5-Hydroxymethyl-2-furaldehyde (HMF); oxidation |
