| 학회 |
한국공업화학회 |
| 학술대회 |
2008년 봄 (05/09 ~ 05/10, 한양대학교(안산)) |
| 권호 |
12권 1호 |
| 발표분야 |
전기화학 |
| 제목 |
Synthesis and Characterization of Polysilane with Double Bonds by Electrochemical |
| 초록 |
Polysilanes with double bonds have been synthesized by the electroreduction of trichloromethylsilane and allyl chloride in a single compartment cell. The polymers have been characterized using FTIR, GPC and 1H NMR. The effects of monomer ratio, monomer concentration, electrode materials, the electrode’s interval time and the amount of supplied electricity were investigated. The results indicate that the ideal molar ratio of MeSiCl3/allyl chloride is 3:1 with Mg electrode material. The molecular weight and yield of polysilanes became higher with increasing of passed charge, shortening of electrode’s interval time, and decreasing of monomer concentrations. |
| 저자 |
오원춘1, 장봉군1, 여미미1, 진명량1, LAI CHEN2, SHI WU2
|
| 소속 |
1한서대, 2Shanghai Univ. |
| 키워드 |
FTIR; GPC; H-NMR
|
| E-Mail |
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