| 학회 |
한국공업화학회 |
| 학술대회 |
2006년 봄 (05/12 ~ 05/13, 전북대학교) |
| 권호 |
10권 1호 |
| 발표분야 |
촉매 |
| 제목 |
Efficient catalytic synthesis of optically pure 1,2-azido alcohols through epoxides ring opening with HN3 |
| 초록 |
A chiral binuclear (salen)Co complexes bearing Lewis acid of group 13 metal chlorides show very high catalytic activity and enantioselectivity for the ring opening of epoxides using HN3 as azide source. It provides a facile and practical synthetic route to a wide range of chiral nonracemic 1, 2-azido alcohols and related compounds in one-pot synthesis with excellent selectivity (92.0- 99.6% ee) under mild conditions. The presence of Lewis acid of group 13 shows strong synergistic effect. |
| 저자 |
진숙위, 김건중
|
| 소속 |
인하대 |
| 키워드 |
1; 2-azido alcohols; Co(salen) complexes; enantioselectivity
|
| E-Mail |
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