| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Effect of Ionic Liquids on Dissociation of Copper Flakes into Copper Nanoparticles and Its Application to Facilitated Olefin Transport |
| 초록 |
Effect of ionic liquids on dissociation of copper flakes into copper nanoparticles and on facilitated olefin transport was investigated. Three different ionic liquids were employed for facile synthesis of copper nanoparticles and for inducing the positive charge density of the copper nanoparticles for facilitated olefin transport. The separation performance of the ionic liquids/Cu metal composite membranes for olefin/paraffin mixtures was in the following order: EMIM+BF4/Cu 〈 BMIM+PF6 /Cu 〈 BMIM+BF4/Cu, surprisingly XPS spectra for the binding energy of the copper atoms in the ionic liquids/Cu metal composite was consistent with the trend for the separation performance. The size distribution of the synthesized copper nanoparticles was evaluated by TEM images and UV-visible spectra. Consequently, it was concluded that facilitated olefin transport was consistent with the trend of increasing binding energy of copper atoms. |
| 저자 |
한국인, 이정현, 박지연, 채일석, 강용수
|
| 소속 |
한양대 |
| 키워드 |
Ionic liquid; Cu nanoparticles; synthesis
|
| E-Mail |
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