화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2017년 봄 (04/26 ~ 04/28, ICC 제주)
권호 23권 1호, p.797
발표분야 열역학
제목 Measurement and Modeling for the 2-(trimethylsilyloxy)ethyl methacrylate and 3-(trimethoxysilyl)propyl methacrylate in supercritical CO2
초록 The Solubilities of 2-(trimethylsilyloxy)ethyl methacrylate) and 3-(trimethoxysilyl)propyl methacrylate) in supercritical CO2 fluid are measured at many different temperature (i.e., 313.2, 333.2, 353.2, 373.2 and 393.2 K) as well as pressures up to 22.49 MPa using variable-volume high pressure view cell by static-type. Their solubility curve in supercritical CO2 fluid is obtained as the temperature increases at a fix pressure. Both systems have shown the type-I phase behavior, and PC-SAFT equation of state (EoS) is used to correlate experimental data. The calculated results with PC-SAFT EoS show a good agreement with experimental data.
저자 이봉섭1, 이재경2, 봉재휘2, 변헌수2
소속 1경남대, 2전남대
키워드 열역학; 상평형; 초임계공정; 상태방정식
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