| 학회 | 한국공업화학회 |
| 학술대회 | 2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 22권 2호 |
| 발표분야 | 정밀화학_포스터 |
| 제목 | Aminolysis of Oxetanes: aluminum amide reagent derived from arylamines |
| 초록 | Research from our own laboratory has focused upon the development of new synthetic pathways using aluminum complex. One widely used reagent of note is dimethylaluminum amide reagent, derived from the reaction between trimethylaluminum and the corresponding amine. We synthesized azacycles from five- and six-membered cyclic ether in preceding study that based on application using aluminum amide reagent. In this synthesis, four-membered cyclic ether(oxetanes) were treated with aluminum amide reagents. Recyclization did not occur between dimethylaluminum amide and oxetane. In ring opening oxetane, derived from a range of arylamines and trimethylalunimum, to afford the corresponding γ-amino alcohols in good yield. |
| 저자 | 최민정, 이상협 |
| 소속 | 대구가톨릭대 |
| 키워드 | Oxetane; Aluminum Amide Reagent |
