화학공학소재연구정보센터
학회 한국재료학회
학술대회 2007년 가을 (11/02 ~ 11/02, 성균관대학교)
권호 13권 2호
발표분야 전자재료
제목 Structural phase transition of Ge2Sb2Te5 cells with TiN electrodes using homemade W heater tip
초록 In these days, wireless communication systems such as mobile telephony have been grown remarkably. The systems require new memory devices having features of low power consumption, fast read/write speed, nonvolatile, and high density. These requirements are a driving force to develop new nonvolatile memories. Phase change random access memory (PRAM) has been regarded as one of the most promising candidates for the wireless communication systems. Phase change random access memory (PRAM), based on the reversible phase change of the chalcogenide alloy, Ge2Sb2Te5 (GST), is widely regarded as a favourite candidate for the next generation memory. The PRAM operation relies on the fact that chalcogenide-based materials can be reversible switched from an amorphous phase to a crystalline state by an external electrical current. So, it is important to study the electrical property according to set/reset cycles, since film thickness shrinkage occurs with the phase transition. In this study, the phase transitions of a GST cell with a volume of 20 x 20 x 0.1 μm3 were carried out by applying a reset pulse (10V and 50ns) and a subsequent set pulse (5V and 300ns) in the SPM equipment using a homemade W heater tip First, commercial AFM tip was used for Joule heating for the phase transition of the GST cell. After several heating processes, the coated conductive layer separated from the Si tip, because of the thermal expansion coefficient mismatch between the adhesion layer and Si tip. This failure made it difficult to evaluate the I-V behaviors. So we fabricated the homemade W heater tip using the focused ion beam (FIB) lithography on the commercial AFM cantilever. The GST phase transformations according to the number of cycles were confirmed by measuring the I-V curves, the cross sectional transmission electron microscope (TEM) observations both before and after applying the programming pulse. The two order difference in the resistance value between the reset and set states was maintained for 105 reset/set pulse cycles. The electron diffraction pattern obtained from the transformed area clearly showed the amorphous state. It is expected that this experimental set-up can be used to evaluate the fatigue behavior of GST cells with reset/set pulse cycles.
저자 김현정1, 최시경1, 강석훈2, 오규환2
소속 1한국과학기술원, 2서울대
키워드 Phase Change Random Access Memory; Ge2Sb2Te5; chalcogenide; scanning probe microscope; phase transition behavior; homemade W heater tip
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