| 학회 |
한국화학공학회 |
| 학술대회 |
2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터) |
| 권호 |
25권 2호, p.2061 |
| 발표분야 |
촉매 및 반응공학 (Catalysis and Reaction Engineering) |
| 제목 |
The initial activity of Pt-Sn/Al2O3 catalyst for propane dehydrogenation with pulse-injection test |
| 초록 |
The dehydrogenation characteristics of alumina supported platinum-tin catalysts were investigated by pulsed injection of propane. The yield of propylene was maximized when the reduction time of propane injection catalyst was 550 ℃. Raman analysis showed that the amount of coke was very small when PtSn (4.5) catalyst was used and the short contact time was simulated by propane pulse injection. As the tin content in the platinum catalyst increased, the propane conversion was lowered, but the selectivity to propylene increased and the yield increased. From this, it can be seen that the tin-added platinum catalyst is less active than the platinum catalyst from the beginning of the reaction, which is less affected by coke. The dehydrogenation reaction by the propane pulse injection shows a higher conversion rate than the result of continuous injection due to the formation of COx, and the amount of coke is very small. Decrease in selectivity due to the formation of COx can be reduced by increasing the reduction temperature and time. |
| 저자 |
Bakhsi Zarghona1, 고형림2, 최이선2, 장진호2
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| 소속 |
1Hankyong National Univ., 2한경대 |
| 키워드 |
촉매 |
| E-Mail |
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| 원문파일 |
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