| 학회 | 한국고분자학회 |
| 학술대회 | 2004년 가을 (10/08 ~ 10/09, 경북대학교) |
| 권호 | 29권 2호, p.82 |
| 발표분야 | 신규고분자 합성 |
| 제목 | Modification of Single-Walled Carbon Nanotube using Atom Transfer Radical Polymerization |
| 초록 | This presentation will describe a method to grow polystyrene from the sidewall of single-walled carbon nanotube (SWNT) in a controlled fashion via Atom Transfer Radical Polymerization (ATRP). Hydroxyl groups on SWNT were first introduced through electrophilic addition of chloroform followed by hydrolysis. Subsequent esterification with 2-chloro-propionyl chloride introduced ATRP initiator on the side wall of SWNT. Grafting polymerization of styrene from initiator-functionalized SWNT via ATRP produced polymer-coated SWNT. Obtained TEM images revealed that after polymerization, about 6 nm-thick polystyrene layer was uniformly formed on SWNT as shown in the below figure. In comparison with the pristine SWNT, polymer-functionalized SWNT showed improved solublity in various organic solvents such as THF, chloroform, methylenechloride, and alcohol. Figure.1 TEM image of polystyrene-grafted single-walled carbon nanotube |
| 저자 | 백현종, 최진환 |
| 소속 | 부산대 |
| 키워드 | Graft polymerization; Single-Walled Carbon Nanotube; Atom Transfer Radical Polymerization |
