화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2010년 봄 (05/13 ~ 05/14, BEXCO(부산))
권호 14권 1호
발표분야 촉매
제목 Tuning the catalytic activity towards the synthesis of cyclic carbonate over polycarbonate using double metal cyanide-ionic liquid catalyst system
초록 Presently, world is concentrating on the activities to the reduced emission of greenhouse gases due to rapid climatic changes. The excellent feedstock properties of CO2 made the scientific communities to consider it as a renewable future carbon resource. Reaction with epoxides has been considered as a useful method for the effective CO2 utilization. Double metal cyanide (DMC) complexes are well-known catalyst for ring opening as well as copolymerization reactions. In this work, the selective production of cyclic carbonate was achieved by the addition of ionic liquid as cocatalyst. The effect of various reaction parameters has been carried out to optimize the reaction conditions.
저자 만주, 최혜지, 박대원
소속 부산대
키워드 Carbon dioxide; Cycloaddition; Double metal cyanides
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