| 학회 |
한국화학공학회 |
| 학술대회 |
2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터) |
| 권호 |
23권 2호, p.2185 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Low Rank Coal Supported Metal (Ni, Rh, Pt, and Pd) Catalysts for Methanol Steam Reforming |
| 초록 |
Catalytic support plays an important role in achieving fundamental virtues of a catalyst; activity, selectivity and life time. Nowadays, carbon materials have been widely used for catalyst support. Low-rank coals (LRCs) that are rich in surface functional groups can be promising catalytic supports; excellent metal dispersion, high coking resistance, and recyclability. In this study, four different metals (Ni, Rh, Pt, and Pd) were dispersed on LRC successfully and their activity for MeOH steam reforming (MSR) was evaluated. Ni and Rh catalysts on LRC gave the best activity for MSR, showing 100% conversion and ＞80% hydrogen yield. Compared to conventional Cu/Zn catalysts, Rh and Ni were less susceptible to thermal sintering, but produced more CO gas. Different metals catalyze different reactions, showing difference in the carbon selectivity. Pt and Pd seem to catalyze methanol decomposition whilst Ni and Rh catalyze MSR and methanation of CO. |
| 저자 |
리아1, 전동혁1, 최호경1, 김상도1, 임정환1, 임영준1, 이시훈1, 이영우2, 유지호1
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| 소속 |
1한국에너지기술(연), 2충남대 |
| 키워드 |
촉매 및 반응공학 |
| E-Mail |
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| 원문파일 |
초록 보기 |
