화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터)
권호 25권 2호, p.1644
발표분야 에너지 환경 (Energy and Environment)
제목 Optical and electrochemical behavior of indanedione based small molecule for organic solar cells
초록 This work reports a new donor-π-acceptor (D-π-A, HBT-TID) type small organic molecule containing thiophene as π spacer, linked with electron deficient indanedione as an acceptor and electron rich hexylbithiophene as donor unit. The synthesized HBT-TID molecule presented good absorption properties by displaying the maximum absorption at ~515 nm in chloroform solution and band gap of ~ 2.07 eV was estimated using the onset value of maximum absorption. The solubility of synthesized HBT-TID molecule was excellent in common solvents which might be associated to the presence of hexylbithiophene unit. The synthesized HBT-TID chromophore showed reasonably suitable highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy level values, which would scale up charge transportation behavior from donor to acceptor units. The synthesized HBT-TID chromophore could be a potential donor material in fabricating the solution processed bulk heterojunction organic solar cells.
저자 알람 샤바즈, 사디아아민, 압둘라, 피자히라미아, 김은비, 장광수, 신형식
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키워드 에너지 환경
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