화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 고분자가공/복합재료
제목 Effect of chemical modification of graphene oxide on mechanical, electrical and thermal properties of Polyimide/graphene oxide nanocomposites
초록 Polyimide (PI) nanocomposites were prepared with exfoliated graphene oxide (GO) and chemically reduced GO (rGO) nanosheets by using polyamic acid (PAA)/GO and PAA/rGO composites as the precursors, and their morphologies and mechanical and electrical properties were explored. The GO was reduced with several reducing agents such as hydrazine, dimethylformamide, and L-ascorbic acid. Graphene has opened up a new opportunity to introduce it into a PI matrix for developing PI-based nanocomposites with superior properties. The possible non-covalent hydrogen bonding (between functional groups of the GO/rGO and those of the PAA) as well as a simultaneous partial in-situ reaction could suppress the phase separation during the thermal imidization process. The prepared PI/GO (rGO) nanocomposites showed improved mechanical, electrical and thermal properties as compared its pure PI. Their properties were strongly correlated with the reduced states of the used rGOs.
저자 하헌욱, 박수영
소속 경북대
키워드 Graphene; Polyimide; nanocomposites
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