| 학회 |
한국고분자학회 |
| 학술대회 |
2003년 봄 (04/11 ~ 04/12, 연세대학교) |
| 권호 |
28권 1호, p.125 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
Radiation-Grafted Ion-Exchange Membranes for Ionomeric Polymer-Metal Composites |
| 초록 |
Ionic membranes have been used as the matrix of ionomeric polymer-metal composites (IPMCs) for bending actuators of artificial muscles. Fluoropolymers with hydrophlilc pendants are appliable to IPMCs polymer matrix. A series of commercial fluoropolymer films were irradiated with γ-rays in order to graft styrene through the bulk after swelling. The influence of the grafting conditions and the initial matrix type was investigated. Styrene-grafted fluoropolymers were sulfonated with chlorosulfonic acid. A degree of sulfonation was determined by the ion-exchange capacity. Thermal analysis and X-ray diffraction experiments were performed to determine the changes in crystallinity and structure during the preparation. Mechanical properties of styrene-grafted fluoropolymers were investigated by universal testing machine and dynamic mechanical analysis. |
| 저자 |
한만재;박종혁;이장열;조재영 |
| 소속 |
서울대 |
| 키워드 |
radiation grafting; fluoropolymer; ionic polymer-metal composites
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| E-Mail |
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