화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 대학원생 구두발표 (발표15분)
제목 Polymer Phase Behavior and Gold-Polymer Complex Nanostructure
초록 In aqueous solution, the amphiphilic block copolymers are easily self-assembled a micelle. The polymer micelles can be controlled by external conditions as a temperature, additive and their mass fraction. The controlled micellar nanostructures can be used to the template for a different substance as a gold nanoparticle (AuNP). The poly(ethylene oxide)-poly(isopropyl glycidyl ether) diblock copolymer was synthesized by anionic ring-opening polymerization, and 4 nm AuNPs were synthesized by Brust method. The small angle x-ray scattering (SAXS) and cryogenic transmission electron microscope (cryo-TEM) measurements investigated that the phases of AuNP-polymer complex. As the results, the AuNPs formed various nanostructures. The AuNP-polymer formed the vesicular nanostructure without complicated procedures. The AuNP-polymer vesicle can be utilized as thermal sensors, imageable drug carriers, carriers for catalysts, and drug or enzyme delivery on the nano- and bio-science.
저자 장종대1, 최수형2, 방준하3, 한영수1, 김태환4
소속 1한국원자력(연), 2홍익대, 3고려대, 4전북대
키워드 Gold nanoparticle; block copolymer; anioic ring-opening polymerization; small angle x-ray scattering; cryogenic transmission electron microscope
E-Mail