화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터)
권호 15권 1호, p.1023
발표분야 촉매 및 반응공학
제목 Preparation of Cu ion doped TiO2 nanotube(TNT) and photocatalytic water splitting under visible light
초록 Nano-sized TiO2 and TNT catalysts were synthesized by using a sol-gel and alkaline hydrothermal method. These catalysts were doped by Cu using impregnation method. The prepared catalysts were characterized by XRD, XPS, FT-IR, BET, FE-SEM, TEM and UV-Vis-DRS. The results showed that nano-sized TiO2 was crystallized to mainly anatase structure; the average particle size was 12 nm, and the particle size was not effected by pH conditions. And TNT catalysts were well crystallized with average diameter of6 nm and average length of several hundred nanometer. The Cu ion doping on photocatalysts greatly increased the absorption of visible light. The enhanced absorption of visible light can be attributed to the charge transfer of 3d electron of Cu ions to the conduction band of TiO2.
저자 강영구, 신기석, 안성환, 함현식
소속 명지대
키워드 TNT; alkaline hydrothermal method; Cu; visible light
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