| 학회 | 한국공업화학회 |
| 학술대회 | 2013년 봄 (05/01 ~ 05/03, ICC JEJU) |
| 권호 | 17권 1호 |
| 발표분야 | 포스터-고분자 |
| 제목 | Influence of the operating conditions on catalytic activity of [PdOAc2(BDOMPP)] in the CO/ethene copolymerization and CO/ethene/1-hexene Terpolymerization |
| 초록 | ABSTRACT : The alternating copolymerization of ethene and carbon monoxide has attracted considerable interest from both academia and industry over the last decades. And diphosphine ligands are among the most active ligands in the synthesis of ethane, CO based polyketones. These catalyst systems are based on the BDOMPP ligand. The influence on the productivity of [PdOAc2(BDOMPP)] in methanol in the CO–ethene copolymerization and on the limiting viscosity number (LVN) of the copolymer of the following reaction parameters has been studied: (1) ratio [Catalyst]/[Ligand]/[Acid]; (2) temperature (3) total pressure at fixed ratio CO/ethene = 1/1; (4) reaction time (5) composition of the water–methanol reaction medium. The catalytic activity of the [PdOAc2(BDOMPP)] complex in the 1-hexene/ethene /CO terpolymerization has been studied in methanol. |
| 저자 | 강원준1, 허성록1, 이원2, 윤근병1 |
| 소속 | 1경북대, 2(주)효성 |
| 키워드 | Palladium complex; Terpolymerization; Polyketone; BDOMPP |
