| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
38권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Effect of the operating conditions on catalytic activity of [PdOAc2(BDOMPP)] in the CO/ethene/α-olefin terpolymerization |
| 초록 |
The alternating copolymerization of ethene and carbon monoxide has attracted considerable interest from both academia and industry over the last decades. Diphosphine ligands are among the most active ligands in the synthesis of ethene, CO based polyketones. These catalytic systems are based on the BDOMPP ligand. It has been studied that the effect of the operating conditions on catalytic acivity, the intrinsic viscosity and melting temperature : (1) ratio [Catalyst]/[Ligand]/[Acid]; (2) temperature (3) total pressure at fixed ratio CO/ethene = 1/1; (4) reaction time (5) composition of the water–methanol reaction medium. Terpolymerization of CO/ethene/α-olefin was also conducted with [PdOAc2(BDOMPP)] complex for reducing melting temperature of polyketone. |
| 저자 |
강원준1, 허성록1, 이원2, 윤근병1
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| 소속 |
1경북대, 2(주)효성 |
| 키워드 |
Palladium complex; Terpolymerization; Polyketone; BDOMPP
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| E-Mail |
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