| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터) |
| 권호 |
34권 1호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
Synthesis and Characterization of Poly(phenylene sulfide)-Grafted Multi-Walled Carbon Nanotubes |
| 초록 |
Generally, poly(phenylene sulfide) (PPS) is synthesized from sodium sulfide and dichlorobenzene at high temperature and high pressure in polar solvents via a conventional condensation polymerization method. In this study, PPS was synthesized from 4-chlorobenzenethiol (CBT) via a self-condensation polymerization method in N-methyl-2-pyrrolidinone as a solvent. PPS-grafted multi-walled carbon nanotubes (PPS-g-MWNT) was also prepared from CBT and the 4-chlorobenzoyl functionalized MWNT. Changes in the thermal and electrical properties of PPS and PPS-g-MWNT were analyzed. Electrical conductivity of PPS and PPS-g-MWNT films increased with the addition of MWNT and doping with AsF5. Tensile strength retentions of the PPS and PPS-g-MWNT films immersed in some acidic (10% of H2SO4 and HNO3) and alkaline (30% of NaOH) solutions at 93ºC for 7 days were exhibited almost 100%. |
| 저자 |
함명조, 홍성돈, 김영호
|
| 소속 |
숭실대 |
| 키워드 |
poly(phenylene sulfide); multi-walled carbon nanotube; grafting; self-condensation polymerization
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| E-Mail |
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