화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터)
권호 16권 2호, p.1621
발표분야 에너지
제목 Development and characterization of Ni based anode for molten carbonate fuel cell
초록 Fuel cell is a device that directly converts chemical energy in the form of a fuel into electrical energy by way of an electrochemical reaction. In the anode for a high temperature fuel cell, nickel or nickel alloy has been used in consideration of the cost, oxidation catalystic ability of hydrogen which is used as fuel, electron conductivity, and high temperature stability in reducing atmosphere.Thereare some gains with decreased temperature in MCFC to diminish the electrolyte loss from evaporation and the material corrosion, which could improve the MCFC life.The two major contributors responsible for thevoltage loss with reducing operation temperature are the ohmic polarization and electrode polarization.The oxidation reaction of hydrogen on an ordinary nickel alloy anode in MCFC is generally considered to take place in the three phase zone. In order to maintain a high performance of the fuel cell, it is necessary to keep this reaction responsible area as wide as possible withthe porosity and specific surface area of the anode at a high level. In this study effective anodes are prepared for MCFCby using zirconium hydride or proton conducting materials at least in part of anode material.
저자 서동호, 박동녘, 윤성필, 남석우, 오인환, 홍성안, 한종희
소속 한국과학기술(연)
키워드 mcfc; anode; low temperature; Three Electrode System
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