화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 분자전자 부문위원회
제목 A Highly Sensitive Optical Sensor for Fe3+ and Cu2+ based on Diketopyrrolopyrrole: Synthesis and Spectral Investigation
초록 Heavy and transition metal (HTM) ions have significant functions in many biological systems and environmental processes. The fluorescent probes for the recognition and the selective detection of HTM ions attract much interest in supramolecular chemistry because of the importance of these ions. Among the HTM ions, recognition of Iron (Fe3+) and copper (Cu2+) is particularly interesting because of their vital roles in biological systems. We have synthesized a series of new π-expanded diketopyrrolopyrrole (DPP)-based fluorescent probes for selective recognition of Fe3+/Cu2+ over a wide range of metal ions. The probe exhibited pronounced on–off type fluoroionophoric properties with significant color change. Both UV-Vis and fluorescence spectroscopic studies demonstrated that probe was highly sensitive and selective towards Fe3+/Cu2+.
저자 홍한나, 이대희, 엄현아, 신지철, 조민주, Matinder Kaur, 최동훈
소속 고려대
키워드 HTM; fluorescent probe; chemosensor
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