| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 가을 (10/06 ~ 10/08, 제주 ICC) |
| 권호 |
39권 2호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
Direct Heteoarylation Polymerization of Thiophene-Based Conjugated Polymers and Their Photovoltaic Applications |
| 초록 |
A series of conjugated polymers of poly(3-alkylthiophene-co-cyanothiophene) with various side chain length were synthesized via direct heteroarylation polymerization in a relatively high yield via simple purification procedure. The addition of cyanothiophene as a comonomer enhanced the intermolecular interaction between neighboring chains and improved the structural perfection of the crystal structure on the substrate. The addition of electron-withdrawing cyanothiophene improved the hole mobility of the poly(3-alkylthiophene)s and displayed good film-forming properties on the various substrates. These polymers were used as a hole transport layer of photovoltaic devices and also measured their performance. The use of these polymers is expected to facilitate the hole transport to the metal anode and effectively block the electron transfer to metal anodes. |
| 저자 |
윤지연, 권순재, 김상용, 황보라, 조서연, 안태홍, 권용구
|
| 소속 |
인하대 |
| 키워드 |
Solar cell; Photovoltaic; Hole transport layer
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| E-Mail |
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