화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO))
권호 22권 1호
발표분야 고분자_포스터
제목 Formation of the Open-Cell Structured Elastomeric Polyurethane Foams using Metal Salt of 12HSA
초록 Foaming processes of an elastomeric polyurethane foam having open-cell structures was investigated using a metal salt of 12-hydroxystearic acid as a reactive cell-opening agent. Lithium salt of 12-hydroxystearic acid (Li-12HSA) was properly prepared by the neutralization reaction of lithium hydrate (LiOH·H2O) with  12-HSA in the presence of silicone base-oil. Heat changes during the foaming process were measured with dynamic DSC. Temperature changes with time  was also measured during the foaming in the center position of an open-mold. As the results, An inflection point was observed at about 40 sec after start of foaming process, indicating the formation of effective cell structures which is starting time for the thermal insulation during the foaming process. Rate of temperature changes to reach the peak temperatures increased linearly with Li-12HSA concentrations, showing that Li-12HSA could play a role for a catalyst as well as the cell opening agent.
저자 안원술
소속 계명대
키워드 Open-Cell Structure; Elastomeric Polyurethane Foam; Cell Opening Agent
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