초록 |
Reversible additionfragmentation chain transfer (RAFT) polymerization of 2,2-dinitropropyl acrylate (DNPA) and 3-azidopropyl methacrylate(AzPMA) was carried out in the present of S-cyanomethyl-s-dodecyltrithiocarbonate (CMDTC) as RAFT agent. This controlled live-radical polymerization exhibited well-controlled molecular weight with narrow polydispersity (PDI < 1.26) , and high conversion. The poly(2,2-dinitropropyl acrylate-co-3-azidopropyl methacrylate) were Characterized by FT-IR, GPC, TGA, DSC, and 1H-NMR. |