화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터)
권호 36권 1호
발표분야 고분자 합성
제목 Copolymerization of 2,2-dinitroacrylates(DNPA) and 3-azidopropyl methacrylate(AzPMA) by RAFT process
초록 Reversible additionfragmentation chain transfer (RAFT) polymerization of 2,2-dinitropropyl acrylate (DNPA) and 3-azidopropyl methacrylate(AzPMA) was carried out in the present of S-cyanomethyl-s-dodecyltrithiocarbonate (CMDTC) as RAFT agent. This controlled live-radical polymerization exhibited well-controlled molecular weight with narrow polydispersity (PDI < 1.26) , and high conversion. The poly(2,2-dinitropropyl acrylate-co-3-azidopropyl methacrylate) were Characterized by FT-IR, GPC, TGA, DSC, and 1H-NMR.
저자 정재철, 이혜림, 이범재, 황택성
소속 충남대
키워드 RAFT; RAFT agnet; Reversible additionfragmentation chain transfer; 2; 2-dinitropropyl acrylate (DNPA)
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