화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2012년 봄 (05/09 ~ 05/11, 김대중컨벤션센터)
권호 16권 1호
발표분야 에너지저장.변환
제목 A study on extending absorption regions and increasing molecular weights of conjugated polymers for photovoltaic application
초록 Photovoltaic cells based on conjugated polymeric materials have many advantages such as flexible properties and large-area substrates, which reduces the manufacturing costs. Generally, CT-type polymers are designed by incorporating donor and acceptor units, since they can absorb as much as solar energy by lowering bandgap. Also long side-chains on the backbone are added for increasing solubility to raise degree of polymerization. In this study, derivatives of quaterthiophene(QT-12) and benzo[c][1,2,5]thiadiazole(BT) was introduced as a donor and acceptor unit, then poly(QT12-alt-oBT) was polymerized via Stille coupling reaction and characterized by UV, CV and GPC.
저자 한명희, 최민희, 송관욱, 문두경, 허정림
소속 건국대
키워드 OPVs; 3; 3'''-didodecyl-2; 2':5'; 2'':5''; 2'''-quaterthiophene(QT-12); conjugated polymers; Stille coupling reaction
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