초록 |
Organoaluminum reagents are of utility value due to their high selectivity, wide application range and excellent reactivity. In our lab, we are interested in research using Alkynylaluminum reagent, the synthesis of N,N-Disubstituted 3-Amino-1,4-diynes and 3-Amino-1-ynes from formamides and N,O-acetal, and the synthesis of α,β-alkynyl ketones from Nitriles were reported. As part of the above study, we report the novel substitution reaction using the cyclic acetal derivative and the Alkynylaluminum reagent. |