| 학회 |
한국공업화학회 |
| 학술대회 |
2007년 봄 (05/11 ~ 05/12, 계명대학교) |
| 권호 |
11권 1호 |
| 발표분야 |
고분자 |
| 제목 |
Novel synthesis and polymerization of 1,3-dioxolane derivative |
| 초록 |
Many functional polymers have been prepared by cationic and radical polymerizations of the 1,3-dioxolanes. The author has found that addition of a nucleophilic compound in the polymerization system was highly effective in suppressing side reaction. The nucleophile acted as a ligand of the terminal cation and decreasde its reactivity to depress the side reactions. It should be noted that nucleophilic compounds played an important role in the cationic living polymerization to suppress the chain-transfer reaction. This polymerization produced only cross-linked products at ambient temperature. |
| 저자 |
박재경1, 김영환1, 김남길1, 김현호2, 김충환3
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| 소속 |
1상주대, 2(주)아코디스, 3수자원공사(연) |
| 키워드 |
polymerization; dioxolane; derivative; nucleophile
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| E-Mail |
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