| 학회 |
한국고분자학회 |
| 학술대회 |
2008년 가을 (10/09 ~ 10/10, 일산킨텍스) |
| 권호 |
33권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Polymerization of Ethynylpyridines by (Bicyclo[2.2.1]hepta-2,5-diene)dichloro Palladium (II) and Properties of the Resulting Poly(ethynylpyridine)s |
| 초록 |
For 2- or 3-ethynylpyridine homopolymers with MeI or EtI, mixing the quaternized polymers with LiTCNQ or TCNQ in acetonitrile and refluxing for 30 min yielded a new type of conjugated polymer. Here, poly(ethynylpyridine)s were prepared by the polymerization of ethynylpyridines with the catalyst of (bicyclo[2.2.1]hepta-2,5-diene)dichloro palladium(II). The instrumental analysis data on the polymer structure revealed that the poly(ethynylpyridine)s have the conjugated polyene backbone structure with pyridyl substituents. The electro-optical and electrochemical properties of the resulting poly(ethynylpyridine)s will be discussed. |
| 저자 |
제갈영순1, 이원철1, 진성호2, 박종욱3, 심상연4, 김상율5
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| 소속 |
1경일대, 2부산대, 3카톨릭대, 4강릉대, 5한국과학기술원 |
| 키워드 |
polyacetylene; conjugated polymer; polymerization
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| E-Mail |
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