화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 봄 (04/25 ~ 04/27, 제주 ICC)
권호 18권 1호, p.937
발표분야 재료
제목 Formation of a nanocomposite between mesostructured cellular silica foam and microporous copper trimesate
초록 A copper-based MOF(Cu3(BTC)2) was formed in the large pores of a COOH-functionalized mesostructured cellular silica foam (MCF(M)-COOH) leading to hydrophobic nanocomposite. The Cu3(BTC)2 was synthesized with the sequential incorporation of Cu(NO3)2•3H2O and 1,3,5-benzenetricarboxylic acid in a water/ethanol mixture containing the MCF(M)-COOH by microwave irradiation. The nanocomposite was characterized by XRD, BET, FT-IR, TEM and solid state 13C-NMR. The formation of the nanocomposite has increased the sorption rate of hydrophobic hydrocarbon vapour as compared with those of pure Cu3(BTC)2 and MCF(M)-COOH as a result of their hybridization.

Reference
1. Y.-K Seo, I. Suryanarayana, Y. K Hwang, N Shin, D.-C A, C.-H Jun and J.-S Chang,. J. Nanosci. Nanotechnol. 2008, 8, 3995.
2. Y.-K Seo, J. W Yoon, U.-H Lee, Y K Hwang, C.-H Jun and J.-S Chang,. Micropore. Mesopre. Mater. in press.
저자 전다혜1, 장종산2, 이지선3, 서유경3, 이우황2
소속 1과학기술연합대, 2한국화학(연), 3연세대
키워드
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