| 학회 |
한국공업화학회 |
| 학술대회 |
2014년 가을 (11/12 ~ 11/14, 엑스코(대구)) |
| 권호 |
18권 2호 |
| 발표분야 |
(국제협력위원회)우수 외국인 연구자를 위한 세션 |
| 제목 |
Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran (DFF) using O2 |
| 초록 |
5-Hydroxymethylfurfural (HMF) is a versatile building block chemical obtained from biomass-derived carbohydrates which can be converted to a wide range of chemicals and fuels. The selective oxidation of HMF leads to 1,2-diforomylfuran (DFF), which finds application in furan based polymers, pharmaceutical intermediates and fine chemicals. The heterogeneous catalysed selective conversion of HMF to DFF is still remains a challenge due to multiple side reactions and separation/purification of DFF from high boiling solvents. Among the low boiling solvents we studied toluene showed maximum HMF conversion of 95% with 95% DFF selectivity MIBK afford ＞95% HMF conversion with ＞95% DFF selectivity. |
| 저자 |
CHURCHIL ANGEL ANTONY RAJJEGANATHAN, 조진구
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| 소속 |
한국생산기술(연) |
| 키워드 |
Biomass; Vanadium; 5-hyroxymethylfurfural (HMF); diformylfuran (DFF); selective oxidation; MIBK
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| E-Mail |
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